摘要
Nanowire coordination polymer cobalt–terephthalonitrile(Co-BDCN) was successfully synthesized using a simple solvothermal method and applied as anode material for lithium-ion batteries(LIBs). A reversible capacity of 1132 mAh g^(-1) was retained after 100 cycles at a rate of 100 mAg^(-1), which should be one of the best LIBs performances among metal organic frameworks and coordination polymers-based anode materials at such a rate. On the basis of the comprehensive structural and morphology characterizations including fourier transform infrared spectroscopy,~1 H NMR,^(13)C NMR, and scanning electron microscopy, we demonstrated that the great electrochemical performance of the as-synthesized Co-BDCN coordination polymer can be attributed to the synergistic effect of metal centers and organic ligands, as well as the stability of the nanowire morphology during cycling.
Nanowire coordination polymer cobalt–terephthalonitrile(Co-BDCN) was successfully synthesized using a simple solvothermal method and applied as anode material for lithium-ion batteries(LIBs). A reversible capacity of 1132 mAh g^(-1) was retained after 100 cycles at a rate of 100 mAg^(-1), which should be one of the best LIBs performances among metal organic frameworks and coordination polymers-based anode materials at such a rate. On the basis of the comprehensive structural and morphology characterizations including fourier transform infrared spectroscopy,~1 H NMR,^(13)C NMR, and scanning electron microscopy, we demonstrated that the great electrochemical performance of the as-synthesized Co-BDCN coordination polymer can be attributed to the synergistic effect of metal centers and organic ligands, as well as the stability of the nanowire morphology during cycling.
基金
supported by Basic Research Project of Shanghai Science and Technology Committee (14JC1491000)
the Large Instruments Open Foundation of East China Normal University
National Natural Science Foundation of China for Excellent Young Scholars (21522303)
National Natural Science Foundation of China (21373086)
National Key Basic Research Program of China (2013CB921800)
National High Technology Research and Development Program of China (2014AA123401)