摘要
研究了伯胺N1923和三苯基氧化膦(TPPO)两个一元萃取剂体系从盐酸介质中萃取AuCl_4^-的动力学.认为两体系的萃取速率均受界面化学反应控制;得到298K时两体系萃取反应的速率常数;计算出萃取反应的活化能.
The kinetics and mechanism of the extraction of gold (Ⅲ) by primaryamine N1923 or triphenylphosphine oxide (TPPO) in chloroform from hydrochloric acid have been Studied in a Stirred Lewis' cell. The experimental results showed that the chemical reactions at the interface are rate-determining steps. The rate constants and activation energies of the reactions were calculated.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1992年第10期989-994,共6页
Acta Chimica Sinica
基金
国家科学基金