N,N-二甲基苯甲醛连氮及其Cu(I)配合物的合成与表征

Synthesis and characterization of N,N-dimethylbenzalazine and its Cu(I) complex

设计合成了一种新的连氮类D-π-D型化合物N,N-二甲基苯甲醛连氮(L1),制备了其双核Cu(I)的配合物,分别用元素分析、红外光谱、核磁共振、电子自旋共振波谱、质谱及电喷雾质谱等进行了表征,并对它们的荧光性质进行了初步研究。

In this paper,a new azine compound,N-dimethylbenzalazine and its Cu(I) complex were designed and synthesized,and characterized by element analysis,IR,1HNMR,ESR,MS and FAB-MS. Structure and fluorescent spectra of ligand L1 and complex Cu2L13(ClO4)2 were studied. The result shows that the kind of the ligand and its copper (I) complex are likely to exhibit third-order nonlinear optical activity.