期刊文献+

2,6-二异丙基萘的合成与分离技术的进展 被引量:10

Advances in Preparation and Separation Technology of 2,6-Diisopropylnaphthalene
下载PDF
导出
摘要 2,6-二异丙基萘(2,6-DIPN)是一种重要的化合物,可用于制取高级聚酯材料和液晶聚合物。本文论述了由萘经选择性烷基化生成2,6-DIPN的研究进展,着重阐述了合成2,6-DIPN所用催化剂的研究;还总结了从异构体中分离2,6-DIPN的方法,并对吸附分离法做了详细阐述;指出由萘作原料,沸石分子筛作催化剂制备2,6-DIPN是石油萘生产的理想的技术方向。 The paper describes the research progress of the preparation methods of 2,6-diisopropylnaphthalene(2,6-DIPN) by the selective alkylation of naphthalene and propylene,and emphasizes on the research development of the catalyst of the synthesis.Subsequently introduces the separation technology of 2,6-DIPN from diisopropylnaphthalene mixtures,among which special details are given to the method of adsorption separation.The paper also points out that the ideal technology of petroleum naphthalene production is preparing 2,6-DIPN from naphthalene and propylene on the zeolite molecular sieve.
出处 《化学工业与工程》 CAS 2003年第3期161-166,共6页 Chemical Industry and Engineering
基金 中国石化集团总公司资助课题(合同号:200024)
关键词 2 6—DIPN 烷基化 沸石分子筛 分离 2,6-diisopropylnaphthalene alkylation zeolite separation
  • 相关文献

参考文献27

  • 1贾宏涛,盛京.PEN聚酯的开发与应用[J].化学工业与工程,1999,16(6):347-353. 被引量:3
  • 2张铭金,陈诵英,沈士德,孙予罕,吴东.沸石分子筛催化剂上萘的择形异丙基化反应性能[J].催化学报,2000,21(2):143-146. 被引量:22
  • 3崔秀菊,李金来,刘桂军.二异丙基萘的研制[J].河北化工,1997(1):20-21. 被引量:2
  • 4杨志才.异丙基萘的三塔分批精馏方法[P].中国:1 112 539A.1995-11-29.
  • 5BRZOZOWSKI R, DOBROWOLSKI J, JAMROZ M,et al. Studies on diisopropyInaphthalene substitutional isomer ism [ J ]. Journal of Molecular Catalysis A:Chemical,2001,170:95 - 99.
  • 6MATHEW I, MAYADEVI S, SABNE S, et al. Studies on isopropylation of naphthaIene over zeoIites[J]. React Kinet Catal Lett, 2001,74 ( 1 ) : 119 -125.
  • 7MOREAU P, FINIELS A, GENESTE P, et al. Selective isopropylation naphthaIene over zeolites[ J ]. Journal of Catalysis, 1992,136 : 487 - 492.
  • 8TOBA M, MIZUKAMI F, NIWA S. Isopropylation of naphthalene over solid acid catalysits [ J ] . Prepr Am Chem Soc Div Pet Chem, 1998,43(2) :278 -279.
  • 9SONG C, SCHMITZ A. Shape- selective isopropylation of naphthalene over mordenite catalysis using MOPA C[J]. Appl Catal A, 1999, 182( 1 ) : 175 -181.
  • 10FERINO 1, MONAC R, ROMBI E, et al. Liquidphase alkylation of naphthalene by isopropanol over zeolites. Par t Ⅱ :Beta zeolites[J]. Applied catalysis A : General, 1999,183 : 303 - 316.

二级参考文献6

共引文献24

同被引文献89

引证文献10

二级引证文献23

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部