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HZSM-5催化的多相酯化法合成氯乙酸甲酯 被引量:1

Heterogeneous Esterification for the Synthesis of Methyl Chloroacetate Catalyzed by HZSM-5 Zeolites
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摘要 The synthesis of methyl chloroacetate from chloroacetic a cid and meth anol over HZSM 5 and modified HZSM 5(i.e. HZSM 5A and HZSM 5B) catalysts has bee n studied. The reaction conditions have been optimized. Over 95% conversions of chloroacetic acid could be achieved at the optimum reaction conditions. The mod ified catalysts with higher acidity in weak acidic region showed relatively high catalytic activities. The synthesis of methyl chloroacetate from chloroacetic a cid and meth anol over HZSM 5 and modified HZSM 5(i.e. HZSM 5A and HZSM 5B) catalysts has bee n studied. The reaction conditions have been optimized. Over 95% conversions of chloroacetic acid could be achieved at the optimum reaction conditions. The mod ified catalysts with higher acidity in weak acidic region showed relatively high catalytic activities.
出处 《分子催化》 EI CAS CSCD 北大核心 2003年第3期209-212,共4页 Journal of Molecular Catalysis(China)
关键词 改性HZSM-5 催化 多相酯化 氯乙酸甲酯 Modified HZSM 5 Zeolites Esterification Methyl chloroace tate
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