摘要
综述了分子氧化剂的醇类液相催化氧化的新进展。分别介绍了均相催化、水/有机两相催化、氟两相催化和液固多相催化体系。重点讨论了精细有机合成中有广泛应用前景的绿色氧化方法。预测了均相催化剂的多相化是今后工业化发展的趋势。
New development in liquid phase catalytic oxidation of alcohols with O2 as the ultimate oxidant was reviewed.Homogeneous,water/organic biphase,fluorous biphase and heterogeneous catalytic systems were discussed respectively,with emphasis on the 'Green'oxidation methods having broad prospects for the synthesis of fine chemicals.The heterogenization of homogeneous catalysis is forecasted to be the industrialization tendencies for alcohols aerobic oxidation.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2003年第3期311-316,共6页
Chemical Research and Application
