摘要
反应进度概念(ζ)已引入到反应热的计算、化学平衡及反应速率的定义式中,但ζ还没有普遍地被引入其它热力学关系式。因此,经过具体推证,将ζ系统地引入了热力学基本方程、对应系数关系式、化学平衡条件、自发方向的判据和平衡移动原理关系式中。并且推出化学亲和势的其它表示形式,从而使主要公式的应用更加规范。
Extent of reaction has been introduced in teaching and researching, but it hasn't universally been drawn into the other relations of Chemical Thermodynamics but for calculations in Thermo-chemistry and definition of reaction' rate. Thus, it has been concretely reasoned to draw into the basic relations of Chemical Thermodynamics, corresponding coefficient, the criterion of the chemical equilibrium and it of the spontaneous reactions' orientation, shifting equilibrium principles, and the other forms of affinity' definition have been out. This made reasoning relations more standard.
出处
《燕山大学学报》
CAS
2003年第2期185-188,共4页
Journal of Yanshan University