邻苯二甲酸根桥联铜多聚配合物的谱学性质与成键状况

Study on spectrum and bond property of phthalate copper polymeric

对邻苯二甲酸根桥联铜多聚配合物{[Cu(phth)(phen)(H_2O)」·H_2O}(Phth表示邻苯二甲酸根二阶阴离子;phen表示1,10-邻菲咯啉)进行了红外光谱和紫外可见光谱研究,探讨了配位中心铜(Ⅱ)离子的成键状况。结果表明,铜与配位原子N、O形成一个畸变的四方锥结构。

In this paper, the phthalate copper polymeric (where Phth is phthalate acid and phen is 1, 10-phenanthroline)has been synthesized. It was studied by elemental analysis, IR and UV - Vis spectrum which indicates that Cu( II ) ion is five coordinated in the complex.