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铼的氧化动力学研究 被引量:7

A Study on Dynamic of Oxidation of Rhenium
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摘要 采用热重分析(TGA)技术分别研究了粉末冶金(PM)Re和化学气相沉积(CVD)Re在空气中的氧化规律。PMRe在1000℃以上的氧化遵循瓦格纳的厚膜氧化规律,即氧化速率遵从抛物线定律;而在较低的温度下,CVDRe的氧化失重与时间呈直线关系。PMRe和CVDRe的氧化失重与温度的关系均符合Arrhenius公式。 The oxidation behavior of PMRe and CVDRe are studied with thermogravimetric analysis(TGA)in air.Wagner law for thick film oxidation is obeyed at above 1 000℃ for PMRe,i.e.between the oxidation rate and the oxidation time exists a parabola relationship.While the temperature is below 1 000℃,a linear dependence exists between them.The relationship between weight loss and temperature for both PMRe and CVDRe are in accordance with Arrheniua plots.
出处 《云南冶金》 2003年第3期22-25,共4页 Yunnan Metallurgy
关键词 粉末冶金 化学气相沉积 氧化 动力学 热重分析 rhenium oxidation dynamics
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参考文献8

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