期刊文献+

环糊精与过渡金属配合物的包合物 被引量:1

The Inclusion Complexs Of Cyclodextrin And Transition Metal Complex
下载PDF
导出
摘要 环糊精及其衍生物不仅与简单客体分子包合 ,也与过渡金属配合物发生包合作用 ,其中环糊精衍生物与过渡金属配合物的包合作用 ,可通过环糊精修饰形成金属离子加冠环糊精主体分子 ,再与有机配体分子包合以及发生相互作用来实现。 Aim Investigation of the cyclodextrin and its derivative inclusion coordination not only with guest molecule, and also with transition metal complexes. Method Inclusion coordination of cyclodextrin derivative with transition metal can be obtained by polishing cyclodextrin to get the metal Capped Cyclodextrin, then inclusion coordinate with organic ligands. Result Cyclodextrin and its derivatives inclusion coordinate with guest molecules product supermoleculers, such as Catenaane, Rotaxane, Polyrotaxane. Conclusion The cyclodextrin inclusion complexes have been extensively investigated and its special function have already been showed in business.
作者 张莉 罗来辉
出处 《巢湖学院学报》 2003年第3期72-75,共4页 Journal of Chaohu University
关键词 环糊精 过渡金属配合物 包合物 包合作用 修饰 Cyclodextrin Transition metal complex Inclusion complex
  • 相关文献

参考文献10

  • 1Hannak R. B,Farber G,Konrat R,Krauter B.An Organometallic Rotaxane and a B12Dimer,Relaxed and Loaded Forms of a Molecular Spring[].Journal of the American Chemical Society.1997
  • 2Kamitori S,Hirotsu K,Higuchi T.Crystal and Molecular Structures of Double Macrocyclic Indusion Complexes Composed of Cyclodextrins, Crown Zthers and Cations[].Journal of the American Chemical Society.1987
  • 3Alston D. R,Slawin A. M. Z,Stoddart J. F,Williams D. J.Stereoselective Nucleophilic additions to a Bicyclic Ketone controlled by a Remote tricarbonyl(diene)iron Moiety[].Angewandte Chemie International Edition.1985
  • 4Manka J. S,and Lawrence D. S.Template-Driven Self-Assembly of a Porphyrin-Containing Suprainole-Cular Complex[].Journal of the American Chemical Society.1990
  • 5Harada A,Li J,Kamachi M.The molecular necklace: a rotaxane containing many threadedα-cyclodextrins[].Nature.1992
  • 6Siegel B,Breslow R.Lyophobic Binding of Substrates by Cyclodextrins in Nonaqueous Solvents[].Journal of the American Chemical Society.1975
  • 7Alston D. R,Slawin D. R,Stoddart J. F,Willams D. J,Zarzycki R.Second -sphere coordination adduces of phosphane-transition metal complexes with β-cyclodextrin and its methylated derivative[].Angewandte Chemie International Edition.1988
  • 8Tabushi I,Shimzu N,Sugimoto T,Shiozuka M,and Yamamura K.Cyclodextrin Flexibly Capped with Metal Ion[].Journal of the American Chemical Society.1977
  • 9Harada A,Li J,Kamachi M.Synthesis of a tubular polymer from threaded cyclodextrins[].Nature.1993
  • 10Trainor G. L,and Breslow R.High Acylation Rales and Engantioselectivity with Cyclodextrin Complexes of Rigid Substrates[].Journal of the American Chemical Society.1981

同被引文献8

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部