摘要
报导了在早期合成1,1' 二羰基二茂铁化合物实验室合成法的基础上,进行规模化合成探索,并用IR,UV,1HNMR,TGA,EPR,XPS及辐照前后红外差谱对其进行系统表征.研究结果表明,经长时间辐照,DAF中有C—H键的断裂.
In this paper, the 1,1'dicarbonylferrocene compounds were synthesized on the basis of previous studies, the commercial scale production was explored, and their properties were systermically characterized by IR,UV, 1H NMR,TGA,EPR,XPS and the infrared difference spectrum before and after irradiation. The results show that there is a break of C-H bond in DAF after a long time's radiation.
出处
《四川师范大学学报（自然科学版）》
CAS
CSCD
2003年第4期393-396,共4页
Journal of Sichuan Normal University（Natural Science）
基金
国家自然科学基金重点资助项目(20134020-01)
关键词
二羰基二茂铁化合物
合成
系统表征
Dicarbonylferrocene Compaunds
Synthesize
Systemtical Characterization
