期刊文献+

低甲醇透过直接甲醇燃料电池 被引量:6

Direct Methanol Fuel Cell with Low Methanol Permeation
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摘要 A Nafion 117 complex membrane with low Pd content was prepared. It was found that at room temperature the diffusivity of methanol through this membrane was reduced to one fifth of that through bare Nafion 117 membrane . The proton conductivity of the modified membrane was also increased, significantly improving the discharge performance of the direct methanol fuel cell(DMFC). A Nafion 117 complex membrane with low Pd content was prepared. It was found that at room temperature the diffusivity of methanol through this membrane was reduced to one fifth of that through bare Nafion 117 membrane . The proton conductivity of the modified membrane was also increased, significantly improving the discharge performance of the direct methanol fuel cell(DMFC).
出处 《应用化学》 CAS CSCD 北大核心 2003年第8期791-793,共3页 Chinese Journal of Applied Chemistry
基金 国家科技部"八六三"( 2 0 0 1AA3 2 3 0 60 ) 国家科技部"九七三"(G2 0 0 0 0 2 5 40 8) 吉林省自然科学基金 ( 2 0 0 0 0 5 10 )资助项目
关键词 直接甲醇燃料电池 Pd-Nafion复合膜 甲醇透过率 direct methanol fuel cell,Pd Nafion complex membrane,methanol permeability
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参考文献8

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同被引文献83

  • 1宋树芹,梁振兴,周卫江,孙公权,辛勤.DMFC的阻甲醇渗透研究进展[J].电池,2004,34(4):292-294. 被引量:6
  • 2邓会宁,许莉,王宇新.磺化杂萘联苯聚醚酮膜的制备及其阻醇和质子导电性能[J].膜科学与技术,2005,25(4):13-16. 被引量:7
  • 3黄绵延,陈华艳,郭剑钊,王志涛,许莉,王宇新.DMFC用PES/SPEEK共混阻醇质子交换膜[J].物理化学学报,2007,23(1):44-49. 被引量:12
  • 4Feichtinger J,Galm R, Walker M, et al. Plasma polymer-ized barrier films on membranes for direct methanol f-uel cells[J]. Surface and Coatings Technology, 2001,142-144 : 181-186.
  • 5Ma Z Q, Cheng P, Zhao T S. A palladium-alloy dep-osited Nafion membrane for direct methanol fuel cells [J]. Journal of Membrane Science, 2003,215 : 327-336.
  • 6Kim Y M, Park K W, Choi J H, et al. A Pd-impregn-ated nanocomposite Nation membrane for use in hlgh-concentration methanol fuel in DMFC[J]. Eleetroehemi-stry Communications, 2003,5 : 571-574.
  • 7Antonucc P L, Ramunni E, Antonucc V, et al. Investig-ation of a direct methanol fuel cell based on a compo-site Nafion-silica electrolyte for high temperature oper-ation[J]. Solid State Ionics, 1999, 125,431-437.
  • 8Tazi B,Savadogo O. Parameters of PEM fuel-cells basedon new membranes fabricated from Nafion , silicotun-gstic acid and thiophene[J]. Electrochimica Acta, 2000,45 : 4329-4339.
  • 9Staiti P, Baglio V, Lufrano F, et al. Hybrid Nation-silica membranes doped with heteropolyacids for application in direct methanol fuel cells[J]. Solid State Ionics,2001,145: 101-107.
  • 10Bauer F, Willert-Porada M. Characterisation of zirconiu-m and titanium phosphates and direct methanol fuel cell (DMFC) perforrnance of functionally graded Nafio-n composite membranes prepared out of them [J]. Power Sources, 2005, 145: 101-107.

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