摘要
以有机主族金属化合物为基本单元进行的超分子自组装是近年来超分子化学的研究方向之一。本文主要对6种主族p区重金属(铟、铊、锡、铅、锑及铋)的典型有机金属超分子的自组装进行探讨和总结。
The self-assembly of supramolecular compounds based on organometallic compounds as building blocks has recently become one interesting research area in supramolecular chemistry. In this review, we focus on those containing six main-group heavy p-block metals (In, Tl, Sn, Pb, Sb, Bi), and illustrate how they are assembled into unusual supramolecular structures via weak interactions, especially secondary bonding and pi interactions.
基金
江苏省教委自然科学基金(02KJB150001)
教育部留学回国人员科研启动基金资助项目
