摘要
在水溶液中合成了标题配合物[Co(pyr)2(sal)2]H2O, 化学式为C24H22N2O5Co,并测定了其晶体结构。晶体属单斜晶系,C2/c空间群。a = 14.654(3),b = 12.247(3),c = 14.060(3) ,β = 116.804(4)°,V = 2252.1(8) 3, Mr = 477.37, Z = 4, Dc = 1.408 g/cm3,μ = 0.800 mm-1,F(000) = 988, Co(Ⅱ)原子是六配位的八面体结构。
The new complex [Co(pyr)2(sal)2]H2O (pyr = pyridine, sal = salicylaldehyde) has been synthesized and its crystal structure was determined to be monoclinic system with space group C2/c by single-crystal X-ray diffraction. a = 14.654(3), b = 12.247(3), c = 14.060(3) , β = 116.804(4)°, V = 2252.1(8) 3, Z = 4, Dc = 1.408 g/cm3 and μ = 0.800 mm-1. In the crystal the Co(Ⅱ) ion is six-coordinated to form an octahedral polyhedron.
