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河流底泥沉积物分子形态综合分析 被引量:14

Comprehensive Speciation Analysis of River Sediment
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摘要 采用BCR连续提取分类法,结合透射电镜、X-ray粉末衍射光谱、红外光谱、原子吸收光谱和相应的化学法等手段,综合分析了山东小清河济南段底泥沉积物的形貌,主要和次要成分的化学组成,并探讨了在BCR分级提取的各个阶段中被提取的底泥试样污染物Cu,Pb,Zn,Cr,Cd的分子存在形态。同时发现污染区底泥试样中硅酸盐晶格内污染元素含量均较本底试样有规律地增加。 Electronic microscopy,X-ray diffraction,infra\|red spectrometry,atomic absorption spectrometry and chemical analysis are used for a comprehensive analysis of the exterior form and the primary,secondary and small component parts of the sediment samples collected from Xiaoqing River in Jinan,Shandong Province.Then with the incorporation of BCR's sequential extraction procedures,a comprehensive analysis and a detailed discussion are made of the molecular forms of the trace metal pollutants such as Cu,Pb,Zn,Cr and Cd in each fractions of the BCR's fractions scheme.It is found that the concentration of the pollution metals in the siliceous crystals in the residual increases regularly with the increase of the concentration of the relevant pollution metals in the sediment.
出处 《环境科学研究》 EI CAS CSCD 北大核心 2003年第3期27-30,共4页 Research of Environmental Sciences
关键词 底泥沉积物 BCR连续提取分类法 CU PB ZN CR CD 综合形态分析 sediment BCR's sequential extraction Cu Pb Zn Cr Cd comprehensive speciation analysis
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参考文献7

  • 1冯素萍,高连存,艾子平,于慧,黄佶,叶新强,王春省.小清河底泥沉积物的形态分析(Ⅰ)——主成分及次要成分分析方法研究[J].山东大学学报(理学版),2001,36(3):319-325. 被引量:3
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二级参考文献5

  • 1Thomas R P,Ure A M,Davidson C M,et al.Three-stage sequential extraction procedure for the determination of metals in river sediments[].Analytica Chimica Acta.1994
  • 2Campos E,Barahona E,Lachica M,et al.A study of the analytical parameters important for the sequential extraction procedure using microwave heating for lead, zinc and copper in callous soils[].Analytica Chimica Acta.1998
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