NMR法研究短链芳烃及其衍生物在胶束中的增溶作用

NMR-STUDIES OF THE SOLUBILISATION OF SHORT CHAIN AROMATIC HYDROCARBONS AND THEIR DERIVATIVES IN MICELLES

本文应用高分辨~1H-NMR谱和相图,研究了十种短链芳烃及其衍生物,在十二烷基硫酸钠胶束中的增溶作用,获得这些增溶物在胶束中的增溶位置和增溶量的详细结果。这对了解这一类增溶物的增溶机理有实际意义。

In the aqueous micellar solution of sodium dodecyl sulfate (SDS ) , the solubilisaton position of ten short chain aromtic hydrocarbons and their derivatives were studied by high resolution proton nuclear magnetic resonance spec-troscopy ( 1H-NMR ) . The content of solubilisate in this aqueous micellar solution were determined from their ternary phase diagrams. The detailed results of position and content of solubilisate were obtained and are discussed theoretically in this paper.