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A New Pathway to Synthesize Cyclomercurated Ferrocenylimines Containing Heterocyclic Ring 被引量：1

A New Pathway to Synthesize Cyclomercurated Ferrocenylimines Containing Heterocyclic Ring
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摘要 The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine. This procedure provides an efficient method for the synthesis of cyclomerucurated ferroceny- limines containing heterocyclic ring which are difficultly synthesized by the conventional method. The reaction mechanism is proposed. The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine. This procedure provides an efficient method for the synthesis of cyclomerucurated ferroceny- limines containing heterocyclic ring which are difficultly synthesized by the conventional method. The reaction mechanism is proposed.
作者 Kun Hua LIN Mao Ping SONG Chen Xia DU Qiao Hong ZHANG Yang Jie WU
机构地区 Department of Chemistry
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第7期673-676,共4页 中国化学快报(英文版)
基金 We are grateful to the National Natural Science Foundation of China(project 20072034) the Natural Science Foundation of Henan Province for the financial support.
关键词 Heterocyclic ring containing cyclomercurated ferrocenylimine synthesis. Heterocyclic ring containing cyclomercurated ferrocenylimine synthesis.
分类号 O626 [理学—有机化学]
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参考文献13

  • 1Y. Wu, S. Hou, J, Gong, X. Cui, L. Ding, etal.,J. Organomet. Chem., 2001, 637-639, 27.
  • 2Y. Wu, J. Hou, H. Yun,X. Cui, R. Yuan,J. organomet. Chem., 2001,637-639,793.
  • 3Y. J. Wu, J. J. Hou, X. C. Liaol Acta. Chimica Sinica.. 2001.59(11):1937.
  • 4Colbran, Stephen B., Robinson, Brain H., Simpson, Jin. Organometallics,1983, 2 (8), 943.
  • 5Y Wu, Y. Liu, K. Ding, H. Yuan, X. Mao, J. Organomet. Chem., 1997, 49, 535.
  • 6X. Cui, Y. Wu, C. Du,L Yang, Tetrahedron: Asmmetry, 1999, 10. 12551.
  • 7R. F. Kovar, M. D. Rausch, J.Organomet.Chem, 1972,35,351.
  • 8Ruhemann, Merriman, J. Chem. Soc., 1905, 87, 1772.
  • 9Y. Q. Huang, H. L. Wang, J. Zhou, Synthesis of Organic Intermediate, Chemical Industry Press, Pekinl, 1997, 330.
  • 10Y. Q. Huang, H. L. Wang, J. Zhou, Synthesis of Organic Intermediate, Chemical Industry Press, Peking, 1997, 393.

同被引文献16

  • 1龚军芳,刘广宇,朱玉,杜晨霞,宋毛平,吴养洁.环钯化二茂铁亚胺-三苯基膦配合物的合成、表征及催化Suzuki反应研究[J].高等学校化学学报,2006,27(7):1266-1271. 被引量：17
  • 2Lopez C,Bosque R,Solans X,et al.Palladium(II)-induced preferential activation of the σ[C2sp(phenyl)-Cl]bond versus σ[C2sp(ferrocene)-H].Crystal structure of[Fe(η5-C5H5){η5-C5H4CH2NCH(C6H3Cl2-2,6)}][J].J.Chem.Soc.,Dalton Trans.,1995,4053-4058.
  • 3Bosque R,Lopez C,Sales J,et al.A bis(cyclopalladated) tetranuclear derivative of methyl ferrocenyl ketone azine:[{Pd[(η5-C5H5)Fe(η5-C5H3)CMeN]Cl(PPh3)}2][J].J.Chem.Soc.,Dalton Trans.,1996,3195-3200.
  • 4Freiesleben D,Polborn K,Robl C,et al.Metal complexes of biologically important ligands.LXXVIII.Synthesis of palladium complexes of ferrocenyl-substituted amino acid derivatives[J].Can.J.Chem.,1995,73:1164-1174.
  • 5Wu Yang Jie,LiuYuan Hong,Ding Kui Ling,et al.Synthesis of cyclopalladated anils of benzoylferrocene via transmetalation reaction of mercurated ferrocenylketimines with Li2PdCl4 or by direct cyclopalladation reaction of ferrocenylketimines[J].J.Organomet.Chem.,1995,505:37-42.
  • 6Li Hong,Wu Yang jie,Yan Wei bo.An efficient catalyst for the synthesis of ortho-substituted biaryls by the Suzuki cross-coupling:Triphenylphosphine adduct of cyclopalladated ferrocenylimine[J].J.Organomet.Chem.,2006,691:5688-5696.
  • 7Xu Chen,Gong Jun Fang,Yue Su Fang,et al.Tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes:synthesis,crystal structures and application in Suzuki and Heck reactions[J].Dalton Trans.,2006,4730-4739.
  • 8Moyano A,Rosol M,Moreno R M,et al.Oxazoline-mediated interannular cyclopalladation of ferrocene:Chiral palladium(Ⅱ) catalysts for the enantioselective aza-Claisen rearrangement[J].Angew.Chem.Int.Ed.,2005,44:1865-1869.
  • 9Wang Hong Xing,Wu Hong Fei,Zhou Hui Chao,et al.Synthesis,characterization of[{(N-methyl-N-benzyl)amino}methyl]ferrocenes and their cyclopalladated complexes:Crystal structure of σ-Pd[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4NO2-4)]Cl(PPh3)[J].Inorganica Chimica Acta.,2006,359(12):4114-4120.
  • 10Concepcion Lopez,Ramon Bosque,Javier Arias,et al.Activation of σ(C-H) bonds of[Fe{(η5-C5H4)-C(Me):N-N:C(H)(C6H3-2,6-R) }2] (withR=Cl or H) promoted by palladium(II)[J].J.Organomet.Chem.,2003,672(1-2):34-42.

引证文献1

Chinese Chemical Letters
2003年 第7期

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