响应面法分析卫生填埋渗滤液的Fenton处理过程

Evaluation of Fenton Process for the Treatment of Sanitary Landfill Leachate with Response Surface Methodology

利用响应面法研究了Fenton试剂处理卫生填埋渗滤液过程中诸因素对COD去除率的影响 ,如渗滤液中高分子量有机物 (HMWOM)与低分子量有机物 (LMWOM)的TOC比例、LMWOM浓度以及双氧水和亚铁离子的摩尔比 (H2 O2 /Fe2 + ) .其中HMWOM/LMWOM值、LMWOM浓度和H2 O2 /Fe2 + 摩尔比值的高、低水平分别为 1 4～ 3 8,975～ 3 0 0 0mg/L ,1 75～ 4 0 0 .由实验数据得到了 1个 2次响应曲面模型 ,该模型显示COD的去除率随着HMWOM/LMWOM值的增加而增加 ,但随着LMWOM浓度的增加而降低 .Fenton试剂处理卫生填埋渗滤液存在着一个最佳的H2 O2 /Fe2 + 摩尔比值 。

Response Surface Methodology (RSM) was employed to investigate the effect of TOC ratio of high molecular weight organic matter (HMWOM) to low molecular weight organic matter (LMWOM), the LMWOM concentration and hydrogen peroxide to ferrous ion molar ratio on COD removal during the treatment of sanitary landfill leachate with Fenton reagents. The high and low levels of HMWOM/LMWOM, the LMWOM concentration and H 2O 2/Fe 2+ were from 14 to 38, 975 to 3000 mg/L, and 1.75 to 4.00 respectively. Using the software of Design-Expert 5, a response surface quadratic model in terms of actual factors was obtained based on the experimental data, and COD removal contour plots were derived from the model accordingly. It showed that COD removal increased with the increase of HMWOM to LMWOM ratio, but decreased with increasing LMWOM concertration. There existed an optimal hydrogen peroxide to ferrous ion molar ratio so that the highest COD removal efficiency could be achieved.