四核钴簇合物[Co_4(mp)_5(PBu_3~n)_3]的快原子轰击质谱碎片和结构的相互关联

The Relation Between the Fragments of FAB-MS of Tetranuclear Cobalt Cluster [Co_4(mp)_5(PBu_3~n)_3] amd Its Structural Parameters

本文通过实验,选择质量1463u、含有四个钴原子具有三种不同配位环境的标题簇合物为研究对象,以快原子轰击软电离方法,探讨质谱碎片与簇合物结构间的相互关联。

The FAB mass spectra of title compound [Co_4(mp)_5(PBu_3n)_3] was studied based on the data of crystal structural parameters and the view of structural Chemistry. The relation between a series of fragment ions and the structural parameters of the title Compound was discussed briefly.