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钙硼复合对土壤锌吸附-解吸热力学和动力学的影响 被引量:2

Effects of Calcium-Boron Interactions on the Thermostatics and Kinetics of Zinc
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摘要 酸性紫色土对锌的等温吸附 -解吸和动力学试验表明 :锌的等温吸附符合 L angmuir方程 ,最大吸附量为15 3.8mg/kg土。钙、硼与锌复合 ,均降低土壤锌的最大吸附量及结合常数 K。所吸持的锌的解吸量和解吸率小 ,钙和硼均降低了锌的解吸率。土壤吸附锌的动力学以 Elovich方程 (Ct=a+blnt)描述最佳 ,反映土壤对锌吸附速率大小的方程参数 b值以 Zn>Zn+Ca+B>Zn+B>Zn+Ca。 Results of thermostatic adsorption and desorption experiments indicated that adsorption of Zn by soil was fitted by Langmiur equation. The adsorption maximum of the sample soil were 153.8 mg/kg. Ca and B tended to decrease adsorption of Zn and constant K. The amounts and rates of Zn desorption from soil were small, and Ca, B decreased the rates of Zn desorption both. The adsorption kinetics of Zn could be described with Elovich Equation. The constant b for different treatments was Ca+B>Ca+B+Zn>Ca>Ca+Zn .
作者 刘金萍
出处 《重庆环境科学》 北大核心 2003年第8期15-17,24,共4页 Chongqing Environmental Science
基金 重庆市科委应用基础研究项目的部分内容 (96- 4 348)
关键词 钙硼复合 热力学 动力学 Zinc Calcium-Boron interactions thermostatics kinetics
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参考文献12

  • 1徐明岗.土壤离子吸附 3.离子吸附的动力学[J].土壤肥料,1998(1):3-6. 被引量:15
  • 2林玉锁.Langmuir,Temkin和Freundlich方程应用于土壤吸附锌的比较[J].土壤,1994,26(5):269-272. 被引量:49
  • 3李学垣主编.土壤化擎及实验指导[M].北京:中国农业出版社,1997..
  • 4Kuo S,Baker A S. Sorption of copper,zinc and cadmium by some acid soils. Soil Sci. Soc. Am. J. ,1980,44:969~974.
  • 5Kinniburgh D G, Jackson M L. Concentration and pH dependence of calcium and zinc adsorption by iron hydrous oxide gel. Soil Sci. Soc.Am. J. ,1982,46:56~61.
  • 6Sparks, D L. Kinetics of Soil Chemical Processes. Academic Press.USA 1989.
  • 7Sparks D L. Soil Pllysical Chemistry. Florida: .CRC Press, Boca Raton, 1986,1~178.
  • 8Sparks D L, Jardine P M. Compartion of kinetics equation to describe potassium-calcium exchang in pure and in mixed system.Soil Sci. ,1984,138:115~122.
  • 9Chien S H, Clayton W R. Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci. Soc.Am.J. ,1980,44:260~264.
  • 10Papadopoulos P,Rowell D L. The reactions of copper and zinc with calcium carbonate surfaces. Journal of Soil Science, UK. , 1989,40(1):39~48.

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