摘要
Using microwave irradiation, perylene was obtained from 3,4,9,10-perylenetetracar- boxylic dianhydride with copper powder in boiling quinoline. With the same method, 1,12- benzoperylene was synthesized from 1, 12-benzoperylene-1, 2-dicarboxylic anhydride, and coronene was prepared from coronene-1, 2- dicarboxylic anhydride with good yield. Through Dields-Alder reaction, 1, 12-benzoperylene-1, 2-dicarboxylic anhydride and coronene-1,2- dicarboxylic anhydride were also prepared using microwave irradiation.
Using microwave irradiation, perylene was obtained from 3,4,9,10-perylenetetracar- boxylic dianhydride with copper powder in boiling quinoline. With the same method, 1,12- benzoperylene was synthesized from 1, 12-benzoperylene-1, 2-dicarboxylic anhydride, and coronene was prepared from coronene-1, 2- dicarboxylic anhydride with good yield. Through Dields-Alder reaction, 1, 12-benzoperylene-1, 2-dicarboxylic anhydride and coronene-1,2- dicarboxylic anhydride were also prepared using microwave irradiation.
