摘要
简要地回顾了近20年来Pd(Ⅱ)、Ni(Ⅱ)金属催化剂在CO/烯烃共聚合应用中的发展状况,并按不同结构配体类别对催化刑的结构、聚合机理等进行了简单的讨论。后过渡金属催化剂的发现,使得CO/烯烃的交替共聚合有了巨大的突破。
This paper briefly reviewed the development status of Pd( Ⅱ) and Ni( Ⅱ) catalysts used in the alternating copolymerization of olefins with carbon monoxide and discussed structures of the catalysts and polymerization mechanism in terms of sorts of the ligands with different structures.
出处
《合成树脂及塑料》
CAS
2003年第4期77-82,共6页
China Synthetic Resin and Plastics