期刊文献+

PX氧化反应动力学模型研究 被引量:3

Research of kinetic model for PX oxidation at high temperature
下载PDF
导出
摘要 建立了一套半连续的PX高温催化氧化反应动力学实验装置,并进行了相关的动力学研究。依据实验数据和机理分析,提出了反应组分抑制的动力学模型。 In this paper a set of semi-batch experiment apparatus was set up for kinetic research of PXcatalytic oxidation at high temperature, and the kinetics of PX oxidation was researched. Upon the analysis of the experimental data and the reaction mechanism, the kinetic model with inhibition of reactants was presented.
作者 张军 程明权
出处 《合成技术及应用》 2003年第2期5-9,共5页 Synthetic Technology & Application
关键词 PX 氧化 动力学 PX oxidation kinetics
  • 相关文献

参考文献8

  • 1盖旭东.乙酸—对二甲苯体系催化氧化动力学研究[J].石油化工,1993,22(11):715-719. 被引量:7
  • 2李希 徐锦龙 张军.高温高压在线取样装置[P].中国专利:012446807.2002—03.
  • 3Partenheimer. W. ,A Chemical Model for the Amoco "MC" Oxygenation Process to Produce Terephthalic Acid, Chem. Ind. (Deckker), 1990,40(Catal.Org.React) ,321-346.
  • 4Cao. G., et al., Kinetics of p-Xylene Liqui-Phase Catalytic Oxidation,AIChE .J. ,40,1156-1166.1994.
  • 5Cao. G., et al., A Lumped Kinetic Model for Liquid-Phase Catalytic Oxidation of p-Xylene to Terephthalic Acid[J]. Chem. Eng. Sci., 49,5775-5783,1994.
  • 6Cincotti,A. ,et al. Effect of Catalyst Concentration and Simulation of Precipitation Processes on Liquid-Phase Catalytic Oxidation of p-Xylene to Terephthalic Acid., Chem. Eng. Sci. ,52,4205-4213,1997.
  • 7Partenheimer. W., Methodology and scope of Metal/Bromide Autoxidawtion of Hydrocarbons[J]. Catalysis Today, 1995,(23).
  • 8Partenheimer. W., The structure of metal/bromide catalysts in acid/water mixtures and its significance in autoxidation, Journal of Molecular Catalysis A: Chemical 174(2001)29-33.

二级参考文献1

  • 1盖旭东,1987年

共引文献6

同被引文献48

引证文献3

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部