手性双核催化剂在不对称合成中的应用研究进展

Progress of Application of Chiral Binuclear Complex Catalyst to the Asymmetric Synthesis

综述了含相同金属的手性双核铑配合物、手性双核钯配合物、手性双核钛配合物、手性双核铜配合物等催化体系在烯烃的环丙烷化、亚胺的烯丙基化、氰硅化、缩合等不对称合成中的应用。

The application of the same metallic chiral binuclear complexes containing rhodium, palladium, titanium, copper and so on to the asymmetric cyclopropanation reaction, cyanosilylation reaction, allylation reaction, aldol reaction and so on is reviewed.