金属催化二氯化物RCCl_2CH_2CH_2R^1合成反应的研究

One-Step Synthesis of RCCl_2CH_2CH_2R^1 from RCC1_3 and CH_2 = CHR^1

在醇溶剂中,用金属或金属合金作为反应的催化剂,多氯化物RCCl_3和含吸电子基的末端烯烃CH_2=CHR^1反应一步生成RCCl_2CH_2CH_2R^1。在此反应中,加成反应和脱氯反应一步完成。

RCCl2CH2CH2R1 were synthesized by one step via the reaction of RCCl3 with CH2 = CHR1 using metal species as catalyst under mild reaction conditions.