摘要
absractThe structure of the title adduct comprises a phenanthroline derivative 2 phenyl imidazo[4,5 f ] 1,10 phenanthroline and a methanol. The composition of the crystalline adduct was cha^racterized as C 19 H 12 N 4·CH 3OH. It belongs to orthorhombic system, space group Pna 2 1 with a =1 3693(4) nm, b = 2 2988(7) nm, c =0 51338(15) nm, V =1 6160(8) nm 3, Z =4, and final R 1=0 0423, wR 2=0 1012. Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar. The bond length data indicated that a very extensive conjugation system was formed. This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.
absractThe structure of the title adduct comprises a phenanthroline derivative 2 phenyl imidazo[4,5 f ] 1,10 phenanthroline and a methanol. The composition of the crystalline adduct was cha^racterized as C 19 H 12 N 4·CH 3OH. It belongs to orthorhombic system, space group Pna 2 1 with a =1 3693(4) nm, b = 2 2988(7) nm, c =0 51338(15) nm, V =1 6160(8) nm 3, Z =4, and final R 1=0 0423, wR 2=0 1012. Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar. The bond length data indicated that a very extensive conjugation system was formed. This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.
基金
theNaturalScienceFoundationofHainanProvinceofChina (No .2 0 0 0 4)
