摘要
Reaction of ( S) α methylbenzylamine with Pd(OAc) 2 in anhydrous HOAc produced the chiral complex [Pd( μ O 2CMe)( S C 6H 4CHMeNH 2)] 2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single crystal X ray analysis. The X ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.
Reaction of ( S) α methylbenzylamine with Pd(OAc) 2 in anhydrous HOAc produced the chiral complex [Pd( μ O 2CMe)( S C 6H 4CHMeNH 2)] 2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single crystal X ray analysis. The X ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.
基金
theNationalNaturalScienceFoundationofChina (No .2 0 172 0 16)
ShanghaiPhosphorProjectofScience&Tech nologyforExcellentYoungResearch (No .0 1QA14 0 17)
theScienceandTechnologyDevelopmentFoundationofShanghai (No .0 1JC14 0 0 2 )
