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碳纤维前驱体聚丙烯腈原丝的亲水改性研究 被引量：1

HYDROPHILIC MODIFICATION OF PAN PRECURSOR OF CARBON FIBER
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摘要 传统方法中一般采用衣康酸(IA)与丙烯腈(AN)共聚合来制备纺丝原液,笔者用衣康酸铵[(NH4)2IA]取代IA与AN共聚。与P(AN co IA)相比,P[AN co (NH4)2IA]的亲水性明显提高,相应的,P[AN co (NH4)2IA]原丝在蒸汽牵伸过程中能承受更高牵伸比,因而纤度低,强度高。笔者研究了(NH4)2IA取代IA后,聚合反应速率和聚合物分子量的变化,并对反应产物进行了亲水性能测试和DSC分析。亲水改性是提高聚丙烯腈原丝性能的一条有效途径。 Chemical modification is an effective method to promote the properties of PAN precursor. In this experiment,(NH4)2IA, instead of conventional IA, was used in the radical copolymerization with AN . The influence of (NH4)2IA to the copolymerization rate and the molecular weight of the copolymer were discussed. The characterization of hydrophilicity and DSC thermal property are also shown. It was discovered that the application of (NH4)2IA could obviously increase the hydrophilicity of the copolymer and the performance of PAN precursor.
作者 刘建军 王成国
机构地区 山东大学材料科学与工程学院
出处 《化工科技》 CAS 2003年第4期1-3,共3页 Science & Technology in Chemical Industry
基金 国家"863"项目(2002AA304130)。
关键词 碳纤维 前驱体 聚丙烯腈 原丝 亲水性能 化学改性 聚合反应 PAN precursor Carbon fiber Chemical modification
分类号 TQ342.742 [化学工程—化纤工业] TQ325.8 [化学工程—合成树脂塑料工业]
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参考文献2

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同被引文献20

  • 1陈光大.碳纤维用PAN原丝的生产和研究[J].吉化科技,1994,2(1):17-21. 被引量：2
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化工科技
2003年 第4期

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