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酸度及碱金属离子在瓜环合成分离中的应用研究 被引量:3

Application Study of Acidity And Alkalime Metal Ion on Synthesis And Separate of Cucurbit[n = 5 -8]urils
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摘要 考察了瓜环在不同酸度、IA金属离子中的溶解性变化情况,并利用其溶解性的变化来合成分离瓜环。结果表明,在一定条件下,选择适当酸度或添加适当金属离子作为模板有利于瓜环的定向合成及分离。 Influence of acidity and IA metal ion on Solubility of Cucurbit [n = 5 -8] urils have been examined. And die experimental results show that the application of acidity and IA metal ion on Solubility of Cucurbit [ n = 5 - 8 ] urils to Synthesis And Separate of Cucurbit [ n = 5 - 8 ] urils usually increases efficiency and decreases cost.
出处 《贵州大学学报(自然科学版)》 2003年第3期303-305,310,共4页 Journal of Guizhou University:Natural Sciences
关键词 瓜环 酸度 金属离子 合成及分离 cucurbit[n]urils acidity metal ion synthesis and separation
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参考文献17

  • 1张桂玲,徐周庆,薛赛凤,祝黔江,陶朱.一类新型环型笼状化合物——瓜环:(Ⅱ)酸度、IA、IIA金属离子对瓜环溶解性的影响[J].无机化学学报,2003,19(6):655-659. 被引量:46
  • 2韩宝航,刘育.葫芦脲:分子识别与组装[J].有机化学,2003,23(2):139-149. 被引量:63
  • 3何强 井文涌 王翊亭.环境学导论(第二版)[M].北京:清华大学出版社,2003..
  • 4刘思敏 严琨 吴成泰.葫[n]环联脲研究进展[A]..大环化学和超分子化学研究进展论文选集[C].西安:西北大学出版社,2002.5-8.
  • 5何强 井文涌 王翊亭.环境学导论(第二版)[M].北京:清华大学出版社,2003..
  • 6Kim J,Jung I S,Kim S Y,Lee E,et al. New Cucurbituril Homologues: Syntheses, Isolation, Characterization, and X -ray Crystal Structures of Cucurbit[n]uril (n = 5, 7, and 8) [J]. J Am Chem Soc , 2000, 122(3) : 540 -541.
  • 7Freeman W A,Mock W L,Shih N Y F. Cucurbituril [J]. JAm Chem Soc,1981,103(24) :7367 -7368.
  • 8Behrend R, Meyer E, Rusche F. Ueber Liebigs [ J ]. Ann Chem, 1905,339 : 1 - 37.
  • 9] Kim H J, Jeon W S , Ko Y H , Kim K. Inclusion of methylviologen in cucurbit [ 7 ] uril [ J ]. Proc Natl Acad Sci , U S A 2002, 99 : 5007 - 5011.
  • 10Jeon W S, Kim H J, Lee C , Kim K. Control of the stoichiometry in host - guest complexatlon by redox chemistry of guests : Inclusion of methylviologcn in cucurbit [ 8 ] uril [ J ]. Chem Commun, 2002 : 1828 - 1829.

二级参考文献77

  • 1Gokel, G. W. In Comprehensive Supramolecular Ohemistry, Vol.1, Eds.: Atwood, J. L.; Davies, J. E. D.; MacNicol, D. D.;Vogtle, F., Pergamon Press, Oxford, 1996, p. 1.
  • 2Szejtli, J.; Osa, T. In Comprehensive Supramolecular Chemistry, Vol. 3, Eds.: Atwood, J. L.; Davies, J. E. D.; MacNicol, D.D.; Vogtle, F., Pergamon Press, Oxford, 1996, p. 1.
  • 3( a ) Gutsche, C. D. In Calixarenes, Monographs inSupramolecular Chemistry, Ed.: Stoddart, J. F., Royal Society of Chemistry, London, 1989, p. 1.(b) Vicens, J.; Bohmer, V. Calixarenes. A Versatile Class of Macrocyclc Compounds, Kluwer Academic Publishers, Dordrecht,The Netherlands, 1991, p. 1.(c) McKervey, M. A.; Schwing-Weill, M.-J.; Amaud-Neu, F. In Comprehensive Supramolecular Chemistry, Vol. 1, Eds.: Atwood, J. L.; Davies, J. E. D.; MacNicol, D. D.; Vogtle, F., Pergamon Press, Oxford, 1996, p. 537. (d) Bohmer, V. Angew. Chem., Int. Ed. Engl. 1995, 34 (7), 713.(e) Danil de Namor, A. F.; Cleverley, R. M.; ZapataOrmachea, M. L. Chem. Rev. 1998, 98(7), 2495.
  • 4(a) Mock, W. L. In Comprehensive Supramolecular Chemistry, Vol. 2, Eds.: Atwood, J. L.; Davies, J. E. D.; MacNicol, D. D.; Vogtle, F., Pergamon Press, Oxford, 1996, p. 477.(b) Mock, W. L. Top. Curr. Chem. 1995, 175, 1. (c) Cintas, P. J. Incusion Phenom. Mol. Recognit. Chem. 1994, 17, 205.
  • 5(a) Gutsche, C. D.; Dhawan, B.; No, K. H.; Muthukrishnan, R. J. Am. Chem. Soc. 1981, 103(13), 3782. (b) Gutsche, C. D.; Iqbal, M. Org. Synth. 1990, 68, 234. (c) Stewart, D. R.; Gutsche, C. D. Org. Prep. Proced. Int. 1993, 25(1), 137. (d) Gutsche, C. D.; Dhawan, B.; Leonis, M.; Stewart, D.Org. Synth. 1990, 68,238.(e) Munch, J. H.; G utsche, C. D. Org. Synth. 1990, 68, 243.
  • 6Behrend, R.; Meyer, E.; Rusche, F. Liebigs Ann. Chem. 1905, 339, 1.
  • 7Freeman, W. A.; Mock, W. L.; Shih, N.-Y. J. Am. Chem. Soc. 1981, 103(24), 7367.
  • 8Freeman, W. A. Acta Crystallogr., Sect. B 1984, 40, 382.
  • 9Busch mann, H.-J.; Fink, H.; Schollmeyer, E. DE 19603377,1997 [ Chem. Abstr. 1997, 127, 205599q].
  • 10Kim, J.; Jung, I.-S.; Kim, S.-Y.; Lee, E.; Kang, J.-K.;Sakamoto, S.; Yamaguchi, K. J. Am. Chem. Soc. 2000, 122 (3), 540.

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