摘要
Newborn two-dimensional materials(NB2DMs) beyond graphene such as transition metal dichalcogenides(TMDs) exhibit excellent optoelectronic and mechanical properties as well as high theoretical specific capacity, which make them become the promising building blocks of flexible energy devices related to energy conversion and storage. Compared to graphene with zero band gap or traditional friable materials such as Si, these NB2 DMs are more suitable to construct flexible devices as active layers of optoelectronic devices or as active materials for batteries. The present review focuses on the recent advances in bendable energy devices based on NB2 DMs, including batteries, supercapacitors(SCs), solar cells, photodetectors and nanogenerators(NGs). The NB2 DMs pave a new way to construct next-generation flexible energy devices with improved performance and we believe that those devices will be seen in our daily life and change our lifestyle in the immediate future.
近年来,智能可穿戴电子产品开始走入我们的日常生活,同时也极大地激发了研究者们对柔性能源的研究兴趣.以过渡金属二硫族化合物为代表的新兴二维材料表现出了优秀的光电和机械性能、高的理论比容量等性质,使其在柔性能源存储和转换领域备受关注.相比于零带隙且比容量低的石墨烯或者硅等传统材料,这些新兴的二维材料在构筑柔性光电器件及二次电池方面具有良好的应用前景.本文综述了新型二维材料在二次电池、超级电容器、太阳能电池、光电探测器和纳米发电机等柔性能源应用领域的突破性进展.虽然目前这个新兴领域仍面临众多问题,但是通过结构与材料的设计与优化,有望在不久的将来逐步得到解决.我们相信这些新兴二维材料的应用将显著提高柔性能源器件的性能,并推动可穿戴电子产品在我们日常生活中的普及.
基金
supported by the National Natural Science Foundation of China(51322209 and 21473124)
Sino-German Center for Research Promotion(GZ871)