摘要
In recent years, mechanoluminescence from polymers is emerging as a new cutting-edge area of polymer mechanochemistry research. It refers to the release of energy from polymers in the form of light when they are under various mechanical stimuli. To spur more researchers to join in such interesting and new burgeoning area, and promote its development to practical applications, in this review, we try to briefly summarize the recent advances in mechanoluminescent polymers with the aspects of non-covalent, covalent,and cascade reactions systems. We pay much attention on the applications of such polymer systems in molecular level failure and stress sensors, and give a perspective of their potential applications in novel energy conversion materials and devices, as well as self-healing materials.
机械力诱导聚合物发光研究的对象是在不同机械作用刺激下,可将机械能转换成光的响应性高分子体系.近年来,这方面的研究已成为新兴的高分子化学研究领域.为吸引更多研究者关注这一领域,推动其进一步发展,本文主要综述了基于非共价键体系、共价键体系和串联反应的机械力诱导发光聚合物的研究进展,重点关注其在损伤探测、应力传感等方面的应用,并展望了力诱导发光聚合物在新型能源转换材料和器件,以及自修复材料等方面的应用前景.
基金
supported by the National Natural Science Foundation of China(51503142)
the Thousand Youth Talents Plan
the Natural Science Foundation of Tianjin(15JCYBJC52900)