硼烷和过渡金属簇合物的稠合规则的研究

Studies on condensation rules for boranes and transition metal clusters

研究了稠合型和非稠合型硼烷、有机金属化合物和过渡金属簇合物所符合的稠合规则.这些稠合规则补充了稀有气体规则、6m+2n电子规则和Wade规则不足之处,扩展了稀有气体规则、6m+2n电子规则和Wade规则的应用范围.讨论了具体影响各种稠合规则的因素如金属原子氧化数和配位数.同时介绍了唐氏硼烷规则、Mingos稠合规则、mno规则和6m+2n电子规则.

This paper researches the condensation rules obeyed by condensed and non-condensed boranes,organometallic compounds,and transition metal clusters. The noble gas rule,6 m + 2 n electron rule and Wade rule are improved by these condensation rules,the application ranges of the noble gas rule,6 m + 2 n electron rule and Wade rule are extended to whole boranes and heterocarboranes. The concrete influence factors are discusses such as transition metal atom oxidation number and coordination number. This paper also introduces Tang's borane rule,Mingos' condensation rule,and mno rule.