烯丙氧基硫逐磷酸酯在GC毛细管中的重排反应研究

Studies on the rearrangement reaction of allyl thionophosphates in GC capillary column

通过对烯丙氧基硫逐磷酸酯GC/MS的质谱研究,首次发现了烯丙氧基硫逐磷酸酯在GC毛细管中的重排反应及其重排规律,由此探索出氮气保护下,在SiO2载体上制备芳氧基烷氧基烯丙硫基硫赶磷酸酯简便有效的新方法.

On the basis of the studies on the GC/MS of allyl thionophosphates, the rearrangement reaction and its regular rearrangement pattern of allyl thionophosphates in GC capillary column were discovered, and afforded the corresponding OarylOmethyl(or ethyl)Sallyl thiolophosphates on SiO2 in N2 in good yields.