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块体非晶合金Fe-Ni-P-B-Ga的制备与性能 被引量:10

PREPARATION AND PROPERTIES OF BULK AMORPHOUS Fe-Ni-P-B-Ga ALLOYS
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摘要 采用助熔剂净化和铜模铸造相结合的工艺,用工业纯原料制备出块体(Fe40Ni40P14B6)100-xGax(x=0-8)合金.样品为直径3mm的圆柱体或宽6 mm、厚1 mm的片材,长度都在10至15 mm左右.XRD与DSC分析表明,x=4-6时易于形成非晶合金.测试表明,这些非晶合金具有优异的耐腐蚀性能和软磁性能.显微硬度测试表明,对相同成分合金,非晶态的显微硬度值比晶态的低.适量Ga的加入,提高了Fe-Ni-P-B合金的非晶形成能力. Bulk (Fe40Ni40P14B6)(100-x)Ga-x alloys with 3 mm diameter rod or 1 mm thickness plate have been prepared by utilizing industrial raw materials, and flux-melting and copper moulding. Differential scanning calorimetry and X-ray diffraction show that the amorphous alloys can formed when x=4-6. The property measurements indicate that the amorphous alloy possess strong corrosion resistance and excellent soft magnetic properties. The microhardness value of the amorphous alloy is lower than that of the crystalline alloy with the same composition. The favorable effect of Ga addition on glass-forming ability of Fe40Ni40P14B6 is also analyzed.
出处 《金属学报》 SCIE EI CAS CSCD 北大核心 2003年第10期1085-1088,共4页 Acta Metallurgica Sinica
基金 华中科技大学人才引进基金资助项目
关键词 Fe—Ni—P—B—Ga块体非晶 显微硬度 耐腐蚀性能 软磁性能 bulk amorphous Fe-Ni-P-B-Ga microhardness corrosion resistance soft magnetic property
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