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Molecular Exchanging Energy of Anionic/Cationic Surfactants System on the Surface of Solution

Molecular Exchanging Energy of Anionic/Cationic Surfactants System on the Surface of Solution
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摘要 In order to study synergism of the mixed surfactants system with molecular exchanging energy (E), the Lennard-Jones formula has been firstly introduced to evaluate the E of the mixed system, CH3(CH2)nOSO 3 /CH3(CH2)nN+(CH3)3 directly from their molecular structure. The comparison of the calculated and the observed results showed that this method is practical. In order to study synergism of the mixed surfactants system with molecular exchanging energy (E), the Lennard-Jones formula has been firstly introduced to evaluate the E of the mixed system, CH3(CH2)nOSO 3 /CH3(CH2)nN+(CH3)3 directly from their molecular structure. The comparison of the calculated and the observed results showed that this method is practical.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第10期1077-1080,共4页 中国化学快报(英文版)
基金 the State Natural Science Foundation of China(No.30070178) the Governor Foundation of Guizhou Province for their financial supports.
关键词 SURFACTANT molecule exchanging energy dimensional crystal model. Surfactant, molecule exchanging energy, dimensional crystal model.
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参考文献4

  • 1M J Rosen. Surfactants and Interracial Phenomena. Wilev: New York. 1987.
  • 2W Z Wang, G Z Li, et al, Chem J Chinese Univ.2002,22, 1225(in Chinese).
  • 3A Q Tang, C D Zhao, et al, Introduction of Statistical Thermodynamics, People Press, Jilin,1983.
  • 4P D T Huibers, Langmuir, 1999, 15, 7546.

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