The Reduction of a Natural Diterpene Containing a, B-Unsaturated Keto Group
The Reduction of a Natural Diterpene Containing a, B-Unsaturated Keto Group
摘要
Hedychenone (1), a diterpene containing a, B-unsaturated keto group, was reduced by aluminum-mercury alloy, and a dimerized product (2) was obtained as the major product. The coupling occurred at B position of the keto group.
Hedychenone (1), a diterpene containing a, B-unsaturated keto group, was reduced by aluminum-mercury alloy, and a dimerized product (2) was obtained as the major product. The coupling occurred at B position of the keto group.
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