摘要
采用65%硝酸/亚硝酸钠体系对六苄基六氮杂异伍兹烷氧化产物四苯甲酰基二苄基六氮杂异伍兹烷(1)和五苯甲酰基一苄基六氮杂异伍兹烷(2)进行亚硝解,脱去了剩余的苄基,将苄基转换为亚硝基,得到了四苯甲酰基二亚硝基六氮杂异伍兹烷(3)和五苯甲酰基一亚硝基六氮杂异伍兹烷(4)。
With the nitrosation of the oxidation products of hexabenzylhexaazaisowurtzitane—tetrabenzoyldibenzylhexaazaisowurtzitane (1) and pentabenzoylmonobenzylhexaazaisowurtzitane (2) by 65% HNO3/NaNO2, the remained benzyl groups were removed successfully, and the corresponding nitrosamine products—tetrabenzoyldinitrosohexaazaisowurtzitane (3) and pentabenzoylmononitrosohexaazaisowutzitane (4) were obtained.
出处
《火炸药学报》
EI
CAS
CSCD
2003年第3期60-61,75,共3页
Chinese Journal of Explosives & Propellants
基金
国防科工委预研基金资助项目(12060451867)
