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水-异丙醚-苯酚三元系46℃等温截面相图的实验测定 被引量:6

Experimental Measurement of Isothermal Section at 46℃ in Water-isopropyl ether-phenol ternary System
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摘要 用气相色谱法实验测定了水_异丙醚_苯酚的三元系在46℃的等温截面相图。相图上呈现两个两相共存区域和一个单相区域。在46℃水和异丙醚存在两相,当逐渐溶入苯酚后,水富端很小,而醚相中异丙醚摩尔分数逐渐减小到25.4%,苯酚逐渐增加到29.0%,这表明在醚相中苯酚可达到较大溶解度。在46℃水和苯酚也存在两相,在三元系中异丙醚在水相和苯酚相中的溶解度都不大。该相图为工业上萃取提供了一定的基础工作。 The isothermal section at 46℃ in water_isopropyl ether_phenol ternary system has been measured experimentally with gas chromatograph method.There are one single_phase region and two two_phase regions in the phase section.At 46℃,there exists two phases in water and isopropyl ether system. With phenol's increasing in solution,the mole fraction of isopropyl ether decreases to 25.4% gradually and the mole fraction of phenol increases to 29.0% gradually in ether phase.It is shown that phenol can get to larger solubility in ether phase and it is very useful for industrial extraction.
出处 《常熟高专学报》 2003年第4期41-44,共4页 Journal of Changshu College
关键词 水—异丙醚—苯酚三元系 46℃ 等温截面 相图 气相色谱法 溶解度 液液平衡 ternary system phase diagram isothermal section Water-isopropyl ether-phenol gas chromatograph method
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  • 1徐新,罗国华,杨春育,张国英.水-异丙醚-苯酚-对苯二酚液液平衡数据的测定及关联[J].石油化工,2001,30(7):538-540. 被引量:14
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  • 4苏裕夫,吕秉玲,王向荣.无机化工生产相图分析[M],北京:化学工业出版社,1985.

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