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浅析六氯环三磷腈合成工艺 被引量:10

Brief introduction of hexachlorotriphosphazene synthesis process
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摘要 介绍了高耗氯的六氯环三磷腈的合成工艺,在比较了三氯化磷-氯化铵-氯气、五氯化磷-氯化铵、五氯化磷-氨气等工艺的特点后,认为氨气法由于产品收率高具有较好的工业化前景。 The synthesis process of hexachlorotriphosphazene, whose chlorine consumption is high, was introduced. The characteristics of several different process was compared. They includes the process of phosphorous trichloride - ammonium chloride - chlorine gas, the process of phosphoric chloride - ammonium chloride, the process of phosphoric chloride - ammonia, et al. It was pointed that because the product yield of ammonia process is high, this process has a better prospect of it's industrialization.
出处 《中国氯碱》 CAS 2003年第10期25-26,共2页 China Chlor-Alkali
关键词 六氯环三磷腈 合成工艺 三氯化磷-氯化铵-氯气 五氯化磷-氯化铵 五氯化磷-氨气 产品收率 hexachlorotriphosphazene phosphoric chloride ammonium chloride ammonia
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参考文献5

  • 1崔小明.聚磷腈要抓紧开发利用[N].中国化工报,2002-12-30(3).
  • 2Fekete, et al. Continuous process for the production of phosphonitrilic chlorides. USP, 4046857, 1977 - 09 - 06.
  • 3Sulzer, et al. Cyclic phoephonitrilic halide process. USP, 4656018.1987 - 04 - 07.
  • 4Tedder Jr.,et al. Trimer process. USP, 4663138. 1987 -05 -05.
  • 5Okamoto Tetsuhiko, et al. Process for the preparation of phosphonitrile chloride oligomer .GB,2154567. 1986 - 01 - 28.

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