摘要
综述了近 2 0多年来手性钛配合物在催化不对称Diels Alder反应中的应用。重点介绍了与钛形成配合物的手性配体二元醇、联萘酚、氨基醇、氨基酸等 ,手性钛配合物在对Diels Alder反应的对映选择性催化方面具有独特的优势。参考文献 2
The application of chiral titanium complexes in the asymmetric Diels Alder reaction was reviewed with 23 references. The chiral ligands such as dihydroxy alcohols, binaphthols, amino alcohols and amino acids were introduced. These titanium complexes showed good enantioselectivity in Diels Alder reaction.
出处
《合成化学》
CAS
CSCD
2003年第5期399-401,416,共4页
Chinese Journal of Synthetic Chemistry
基金
衡阳师范学院资助项目