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A New Synthetic Strategy to Prepare a Polyphosphazene with Charge-Transporting Agents and Nonlinear Optical Chromophores as Side Chains

A New Synthetic Strategy to Prepare a Polyphosphazene with Charge-Transporting Agents and Nonlinear Optical Chromophores as Side Chains
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摘要 A new strategy, a post coupling method to develop the polyphosphazene (P2) functionalized with carbazolyl groups and nonlinear optical (NLO) chromophores, has been explored. P2 exhibits good solubility in common organic solvents. The poled film of P2 exhibits a resonant d 33 value of 42 pm/V by second harmonic generation (SHG) measurements. A new strategy, a post coupling method to develop the polyphosphazene (P2) functionalized with carbazolyl groups and nonlinear optical (NLO) chromophores, has been explored. P2 exhibits good solubility in common organic solvents. The poled film of P2 exhibits a resonant d 33 value of 42 pm/V by second harmonic generation (SHG) measurements.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2003年第10期1395-1399,共5页 中国化学(英文版)
基金 ProjectsupportedbytheEducationMinistryofChinaandHubeiProvince (Nos .2 0 0 3ABA0 74,2 0 0 3× 10 7)
关键词 post coupling method POLYPHOSPHAZENE synthesis post coupling method, polyphosphazene, synthesis
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参考文献3

  • 1Zhen Li,Jingdong Luo,Jun Li,Caimao Zhan,Jingui Qin.Novel polyphosphazenes containing charge-transporting agent and chromophore as pendant groups[J].Polymer Bulletin.2000(2)
  • 2Allcock,H. R. Chemical and Engineering News . 1985
  • 3Allcock,H. R. Appl . Organomet . Chem . 1998

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