摘要
研究了草酰胺桥联双核铜配合物和不同表面活性剂胶束组成的金属胶束催化PNPA水解的动力学特征。结果表明:金属胶束催化PNPA水解为双分子反应;不同配体结构的配合物的催化活性不同;三种不同类型表面活性剂胶束对催化PNPA水解的影响也不同。
The kinetics characteristi on PNPA hydrolysis catalyzed by the metallomicelle made of oxamido-bridged dinuclear copper(Ⅱ) complex and the micelle was studied in the paper.The results indicated:PNPA catalytic hydrolysis in the metallomicelles is the dimolecular reaction;the catalytic activities of different construct complexes are different for PNPA catalytic hydrolysis;the three different surfactant micelles used in the study revealed different catalyese in PNPA hydrolysis.The results also showed that the PNPA catalytic hydrolysis mechanism and the kinetic model proposed in the paper were reasonable.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2003年第5期643-646,共4页
Chemical Research and Application
基金
国家自然科学基金资助项目(No.29873031
20173038)
自贡师范高等专科学校校级课题资助。
