摘要
水杨醛缩氨基硫脲与三碘化锑、三碘化铋通过固相反应,合成了新的配合物[SbI3(C8H9N3OS)],[BiI3(C8H9N3OS)]。经元素分析、X 射线粉末衍射,中红外、远红外光谱和差热 热重分析,确定了其组成和结构。对XRD谱进行指标化,确定了配合物的晶系和晶胞参数。
Salicylaldehyde thiosemicarbazone complexes of antimony (Ⅲ)and bismuth(Ⅲ), and ,were synthesized by solid phase reaction.The complexes were characterized by elemental analysis,Xray powder diffraction,IR spectra and DTATG.The crystalline structure of the complexes belonged to monoclinic system.The lattice parameters werea=12988nm,b=15822nm,c=19509nm,β=943°for ,and a=13068nm,b=15854nm,c=19482nm,β=9404° for .In the complexes,N,O,S and I atoms coordinate to the Sb or Bi ion.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2003年第5期631-634,共4页
Chemical Research and Application
关键词
水杨醛缩氨基硫脲
锑配合物
铋配合物
固相合成
XRD谱
salicylaldehyde thiosemicarbazone
antimony(Ⅲ)
bismuth(Ⅲ)
complex
solid phase synthesis
XRD spectra