水杨醛缩氨基硫脲合锑(Ⅲ)、铋(Ⅲ)配合物的固相合成

Solid phase synthesis and characterization of salicylaldehyde thiosemicarbazone complexes of Sb(Ⅲ) and Bi(Ⅲ)

水杨醛缩氨基硫脲与三碘化锑、三碘化铋通过固相反应,合成了新的配合物[SbI3(C8H9N3OS)],[BiI3(C8H9N3OS)]。经元素分析、X 射线粉末衍射,中红外、远红外光谱和差热 热重分析,确定了其组成和结构。对XRD谱进行指标化,确定了配合物的晶系和晶胞参数。

Salicylaldehyde thiosemicarbazone complexes of antimony (Ⅲ)and bismuth(Ⅲ), and ,were synthesized by solid phase reaction.The complexes were characterized by elemental analysis,Xray powder diffraction,IR spectra and DTATG.The crystalline structure of the complexes belonged to monoclinic system.The lattice parameters werea=12988nm,b=15822nm,c=19509nm,β=943°for ,and a=13068nm,b=15854nm,c=19482nm,β=9404° for .In the complexes,N,O,S and I atoms coordinate to the Sb or Bi ion.