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一类高速固化光敏树指的合成及表征 被引量:5

Synthesis and characterization of a new type high speed curable photocurable resin
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摘要 A novel type of photocurable resin was sythesis through Michael addition of acrylate containing polybasic double bond such as TMPTA with polybasic aliphatic amine such as ethylenediamine and triethylenetetraamine,which was characterizaled by 1HNMR,FT-IR,GPC and UV-curable experment.The result showed that the photocurable resin was a mixture of active diluent e.q.TMPTA and in situ have produced oligomers with different molecular weight containing polybasic double bond,so that it has rather low viscosity and high curing speed. A novel type of photocurable resin was sythesis through Michael addition of acrylate containing polybasic double bond such as TMPTA with polybasic aliphatic amine such as ethylenediamine and triethylenetetraamine,which was characterizaled by 1HNMR,FT-IR,GPC and UV-curable experment.The result showed that the photocurable resin was a mixture of active diluent e.q.TMPTA and in situ have produced oligomers with different molecular weight containing polybasic double bond,so that it has rather low viscosity and high curing speed.
出处 《化学研究与应用》 CAS CSCD 北大核心 2003年第5期718-720,730,共4页 Chemical Research and Application
关键词 高速固化 光敏树脂 合成 表征 丙烯酸酯 迈克尔加成 photocurable resin curable acrylate Michael addition
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