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手性二噁唑啉吡啶铁和镍配合物的制备与表征 被引量:2

Preparation and Characterization of Chiral Bis(oxazolinylpyridine) Nickel(Ⅱ) and Iron(Ⅱ) Complexes
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摘要 Tridentate bis(oxazolinylpyridine)(1) reacted with nickel chloride or ferrous chloride in anhydrous ethanol to form bis(oxazolinylpyridine) Nickel? and Iron? complexes. The stable solid complexes were characterized with IR, UV, MS, XPS and elemental analysis. No stable complexes were formed with bidentate bis(oxazoline)(2) ins tead of bis(oxazolinylpyridine). Tridentate bis(oxazolinylpyridine)(1) reacted with nickel chloride or ferrous chloride in anhydrous ethanol to form bis(oxazolinylpyridine) Nickel? and Iron? complexes. The stable solid complexes were characterized with IR, UV, MS, XPS and elemental analysis. No stable complexes were formed with bidentate bis(oxazoline)(2) ins tead of bis(oxazolinylpyridine).
机构地区 厦门大学化学系
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2003年第11期1207-1211,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.29772029) 福建省自然科学基金资助项目(No.C991002) 教育部骨干教师基金资助项目。
关键词 手性二噁唑啉吡啶 铁配合物 镍配合物 制备 表征 二噁唑啉 bis(oxazoline) bis(oxazolinylpyridine) bis(oxazolinylpyridine)nickel complex bis(oxazolinylpyridine)iron complex
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