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含聚氨基双马来酰亚胺耐热固化剂的环氧-亚胺胶液 被引量:1

EPOXY-IMIDE GLUE CONTAINING POLYAMINOBISMALEIMIDE AS A CO-CURING AGENT
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摘要 双马来酰亚胺与芳香胺先行溶液预聚合,生成的聚氨双马来酰亚胺(PABMI)作为耐热固化剂,与环氧树脂共混制成一系列单组分透明胶液。研究了不同比例的这种环氧-亚胺树脂的共固化反应性、粘结性和固化树脂的耐热性。结果表明,PABMI使环氧树脂耐热性明显提高,随着环氧树脂比例增加,固化加快,粘结性增大,耐热性降低,建议了不同耐热等级时的原料比例。 A series of epoxyimide monocomponent transparent glue had been obtained through the reaction of epoxy resin with polyaminobismaleimides(PABMI)as a epoxy curing agent derived from bismaleimide and aromatic amines.The effects of material ratio and curing temperature on the reactivity,adhesion and the heatresistance of cocured resins were investigated for each epoxyimide glue system.The result showed that PABMI made the heat resistance of thermosets increased obviously With the content of epoxy resin increased,the curing rate and its viscosity were increased,but the heat resistance decreased.The raw material ratio of the glue with the different heat resistant level was determinated.
出处 《热固性树脂》 CAS CSCD 2003年第5期13-15,共3页 Thermosetting Resin
关键词 环氧-亚胺树脂 聚氨双马来酰亚胺 反应性 粘结性 耐热性 epoxy-imide resin polyaminobismaleimide reactivity adhesion heat-resistance
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  • 1刘建华.双马来酰亚胺改性环氧树脂的固化行为及性能[J].绝缘材料通讯,1996(3):41-45. 被引量:3
  • 2刘润山.双马来酰亚胺型耐热粘合剂及其发展[J].粘合剂,1984,(3):16-23.
  • 3M N Sand, R K Gupta, S V Raman, et al. An aromatic amine as a Co-Curing agent in epoxy-bisimide blends [J]. Appl Polym Sci, 1993, 49: 1131-1144.
  • 4Mallet M A J, et al. Polyaminobismaleimides [C]. New industrial Polymers ACS Symp Ser, 1974, 4: 112.

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