杯冠化合物在处理高放废液中的应用(Ⅰ)——新型萃取剂异丙氧基杯[4]冠-6的合成与表征

Vovel Extractant Calixcrown Used in High-level Liquid Waste (Ⅰ)——Synthesis of Bis(2-propyloxy)calix crown-6

研究以对叔丁基苯酚和甲醛等作为初始原料合成中间体对叔丁基杯[4]芳烃、杯[4]芳烃和异丙氧基杯[4]芳烃;以二缩三乙二醇和氯化亚砜等作为初始原料合成中间体二氯代三甘醇、五甘醇和五甘醇对甲苯磺酸酯。最后,由异丙氧基杯[4]芳烃和五甘醇对甲苯磺酸酯合成了目标产物二(2 丙氧基)杯[4]冠 6,对合成的各种中间体和目标产物进行了表征。

Synthesis procedure of various intermediates of bis (2propyloxy)calixcrown6(1,3alernate) is suggested and studied. They are ptertbutylcalixarene, calix\axene, bis(2propyloxy)calix\arene, triethylene glycol dichloride, pentaethylene glycol and oligoethylene glyeol ditosylate. All the compounds are determined mainly by IR and 1H NMR. 