溶剂束缚球假说对稀溶液依数性的解释

The Explanation of Colligated Properties of Thin Solution through Fettered Solvent's Spheroid Hypothesis

目的:从溶质和溶剂粒子之间的作用力和溶液的凝聚态解释稀溶液依数性。方法:根据拉乌尔定律提出后100多年来发现的实验事实,分析溶质和溶剂粒子的受力情况和凝聚态。结果:提出了“溶剂束缚球”假说,成功地解释了稀溶液依数性产生的原因,指出了拉乌尔定律错误的根源。结论:溶剂束缚球和分子平均缔合度是产生稀溶液依数性的原因。

Purpose:To explain colligated properties of thin solution by the way of applied force between solute and solvent povrticles and condensed state of solution.Method:To analyze the applied force between solute and solvent particles and the condensed state of sdution according to the experimental findings over100years after Raoult Law put forward.Result:The hypothesis of fettered solvent's spheroid successfully interprets the causes of the development of colligated properties of thin solution and analyses the roots of the Raoult Law.Conclusion:Fettered solvent's spheroid and average molec-ular association level is the main reason for producing colligated properties of thin solution.