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参比电极体系内阻对电化学阻抗谱的影响 被引量:13

EFFECT OF INTERNAL RESISTANCE OF REFREENCE ELECTRODE SYSTEM ON ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY(EIS)
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摘要 在参比电极体系有无鲁金毛细管的条件下 ,测定了 316不锈钢在不同浓度NaCl溶液中的电化学阻抗谱 . The extraneous high-frequency phase shifts in EIS can obscure experimental data and cloud the true analysis of a spectrum. So it is very important to discern the artifacts resulted from various factors during experiment and analysis. The EISs of 316 stainless steel in NaCl solutions of different concentrations were measured with and without Luggin capillary. The results showed that the large internal resistance of the reference electrode system induced capacitive high-frequency phase shift in impedance measurement. It was also observed that high-frequency phase shifts were reduced with the decrease of solution resistance and the internal resistance of reference electrode system.
出处 《腐蚀科学与防护技术》 CAS CSCD 北大核心 2001年第3期125-127,共3页 Corrosion Science and Protection Technology
基金 国家重点基础研究项目资助 !(G2 0 0 0 0 2 64 0 9)
关键词 电化学阻抗谱 高频相移 参比电极体系 鲁金毛细管 不锈钢 EIS,high-frequency phase shift,reference electrode system,luggin capillary
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参考文献5

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