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由邻苯二酚合成愈创木酚的反应过程和动力学研究 被引量:9

Reactive Process and Kinetic Studies on Synthesis of Guaiacol with Catechol and Methanol
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摘要  在连续固定床反应器中,以复合的固体酸为催化剂,以邻苯二酚和甲醇为原料,在270~300℃下进行了气固催化合成愈创木酚的反应过程研究,通过对实验结果进行分析,给出了适宜的反应条件并关联出了与实验吻合的宏观动力学方程。 The reactive process of synthesis of guaiacol with catechol and methanol using solid acid catalysts at the temperatures of 270~300℃ was studied in a fixed bed reactor. Kinetic equations in good agreement with experiments and suitable reaction conditions were obtained by analyzing and regressing the experimental data.
作者 王成习
出处 《化学反应工程与工艺》 CAS CSCD 北大核心 2003年第3期248-253,共6页 Chemical Reaction Engineering and Technology
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  • 1陈光文,袁权.硅橡胶/陶瓷复合膜反应器中CO_2合成甲醇(Ⅰ)反应动力学[J].化工学报,2002,53(1):17-22. 被引量:9
  • 2Vdovtsova E A, Koehetkova E A, Limankina N L, et al. Vapor-phase Alkylation of Pyroeatechol and Guaiaeol with Methanol[J]. Khim. Farm. Zh. 1987, 21(12): 1480-1483.
  • 3Bhatnagar S P, Prakash A, Misra S C, et al. Process for Preparation of Monoalkoxyphenols[P]. Indian IN 158895, 1987.
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  • 5Shiomi Y, Nakamura Y, Manabe T, et al. Method of Producing a Monoalkylether of a Dihydric Phenol Compound[P]. Eur.Pat. Appl. EP509927,1992.
  • 6Kiwi-Minsker L, Jenzer G, Pliasova L, et al. Selective C-and O-methylation of Catechol in Gas Phase over Modified C-alumina[J]. Stud. Surf. Sci. Catal. 1999, 121: 159-164.

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